Use list attributes to simpify everything:
from daylight import Smiles, Smarts
pat = Smarts.compile("CC[N,C]")
mol = Smiles.smilin("OCCCN") # made-up molecule
paths = pat.match(mol)
for path in paths:
for atom in path.atoms:
print atom.symbol,
print
Compare this Python code with the C code on the next page.